Plant MaterialsDOE-HDBK-1017/2-93SHIELDING MATERIALSWater also provides a ready means for removing the heat generated by radiation absorption. Athigher energies (10 MeV), the cross section for interaction with hydrogen (1 barn) is not aseffective in slowing down neutrons. To offset this decrease in cross section with increasedneutron energy, materials with good inelastic scattering properties, such as iron, are used. Thesematerials cause a large change in neutron energy after collision for high energy neutrons but havelittle effect on neutrons at lower energy, below 0.1 MeV.Iron, as carbon steel or stainless steel, has been commonly used as the material for thermalshields. Such shields can absorb a considerable proportion of the energy of fast neutrons andgamma rays escaping from the reactor core. By making shields composed of iron and water, itis possible to utilize the properties of both of these materials. PWRs utilize two or three layersof steel with water between them as a very effective shield for both neutrons and gamma rays.The interaction (inelastic scattering) of high energy neutrons occurs mostly with iron, whichdegrades the neutron to a much lower energy, where the water is more effective for slowingdown (elastic scattering) neutrons. Once the neutron is slowed down to thermal energy, itdiffuses through the shield medium for a small distance and is captured by the shielding material,resulting in a neutron-gamma (n,g) reaction. These gamma rays represent a secondary source ofradiation.Iron turnings or punchings and iron oxide have been incorporated into heavy concrete forshielding purposes also. Concrete with seven weight percent or greater of water appears to beadequate for neutron attenuation. However, an increase in the water content has the disadvantageof decreasing both the density and structural strength of ordinary concrete. With heavy concretes,a given amount of attenuation of both neutrons and gamma rays can be achieved by means ofa thinner shield than is possible with ordinary concrete. Various kinds of heavy concretes usedfor shielding include barytes concrete, iron concrete, and ferrophosphorus concrete with variousmodified concretes and related mixtures. Boron compounds (for example, the mineralcolemanite) have also been added to concretes to increase the probability of neutron capturewithout high-energy gamma-ray production.Boron has been included as a neutron absorber in various materials in addition to concrete. Forexample, borated graphite, a mixture of elemental boron and graphite, has been used infast-reactor shields. Boral, consisting of boron carbide (B4C) and aluminum, and epoxy resinsand resin-impregnated wood laminates incorporating boron have been used for local shieldingpurposes. Boron has also been added to steel for shield structures to reduce secondary gamma-ray production. In special situations, where a shield has consisted of a heavy metal and water,it has been beneficial to add a soluble boron compound to the water.GammaRadiationGamma radiation is the most difficult to shield against and, therefore, presents the biggestproblem in the reactor plant. The penetrating power of the gamma is due, in part, to the fact thatit has no charge or mass. Therefore, it does not interact as frequently as do the other types ofradiation per given material. Rev. 0Page 19MS-05
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