OPERATION AND CONSTRUCTIONDOE-HDBK-1084-95Lead-Acid Storage BatteriesBatteriesPage 18Rev. 0 Figure 8. Changes in voltage and specific gravity during charge and discharge.Therefore, during fully charged steady-state operation and on discharge, measurement of thespecific gravity of the electrolyte provides an approximate indication of the state of charge ofthe cell. The downward sloping line for the specific gravity during discharge is approximatedby the equation below:Specific gravity = cell open-circuit voltage - 0.845(5)orCell open circuit voltage = specific gravity + 0.845.(6)The above equations permit electrical monitoring of approximate specific gravity on anoccasional basis. As mentioned earlier, specific gravity measurements cannot be taken onsealed lead-acid batteries. Measurement of the cell open-circuit voltage has been used as anindicator of the state of charge of a sealed battery. More reliable methods for determining thestate of charge of sealed batteries are under development. The specific gravity decreases during the discharging of a battery to a value near that of purewater and it increases during a recharge. The battery is considered fully charged whenspecific gravity reaches it's highest possible value.Specific gravity does, of course, vary with temperature and the quantity of electrolyte in acell. When the electrolyte is near the low-level mark, the specific gravity is higher thannominal and drops as water is added to the cell to bring the electrolyte to the full level. The
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